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L'objectif de l'étude est de proposer un cadre juridique propice à la biosécurité de Wallis et Futuna, qui réinvestisse les dispositions préexistantes en les étoffant et les renforçant. Cela répond à un contexte où les textes relatifs à la biosécurité de Wallis-et-Futuna étais épars, hétérogènes et en partie obsolètes. Les enjeux de biosécurité poussent à la réflexion vers un corpus complet, cohérent et actualisé en la matière. Le droit international et régional, notamment les directives de Port-Moresby de 2007, permettent d’alimenter la réflexion en la matière. Pour réaliser cette proposition ont été réalisés : (i) des entretiens, (ii) des analyses bibliographiques et synthèses de doctrine, de droit comparé, de droit régional, de droit international, proposition légistique et (iii) des analyses bibliographiques, propositions de listes et de fiches techniques.

We present a list of Chemicals of Concern (CoCs) in plastic toys. We started from available studies reporting chemical composition of toys to group plastic materials, as well as to gather mass fractions and function of chemicals in these materials. Chemical emissions from plastic toys and subsequent human exposures were then estimated using a series of models and a coupled near-field and far-field exposure assessment framework. Comparing human doses with reference doses shows high Hazard Quotients of up to 387 and cancer risk calculated using cancer slope factors of up to 0.0005. Plasticizers in soft plastic materials show the highest risk, with 31 out of the 126 chemicals identified as CoCs, with sum of Hazard Quotients > 1 or child cancer risk > 10􀀀 6. Our results indicate that a relevant amount of chemicals used in plastic toy materials may pose a non-negligible health risk to children, calling for more refined investigations and more human- and eco-friendly alternatives. The 126 chemicals identified as CoCs were compared with other existing regulatory prioritization lists. While some of our chemicals appear in other lists, we also identified additional priority chemicals that are not yet covered elsewhere and thus require further attention. We finally derive for all considered chemicals the maximum Acceptable Chemical Content (ACC) in the grouped toy plastic materials as powerful green chemistry tool to check whether chemical alternatives could create substantial risks.

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